MATHESON TRI-GAS, INC. -- O-XYLENE -- -
===================== Product Identification =====================
Product ID:O-XYLENE
MSDS Date:Jan 24 1989
Kit Part:=== Responsible Party ===
Company Name:MATHESON TRI-GAS, INC.
Address:959 ROUTE 46 EAST
City:PARSIPPANY
State:NJ
ZIP:07054-0624
Country:US
Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON)
780-471-4036
Chemtrec Ind/Phone:18004249300
=== Contractor Identification ===
Company Name:MATHESON TRI-GAS, INC.
Address:959 ROUTE 46 EAST
Box:City:PARSIPPANY
State:NJ
ZIP:07054-0624
Country:US
Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON)
780-471-4036
CAGE:Company Name:MATHESON TRI-GAS, INC.
Address:530 WATSON STREET
Box:City:WHITBY
State:ZIP:L1N 5R9
Country:ONTARIO, CANADA
Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON)
780-471-4036
CAGE:
============= Composition/Information on Ingredients =============
Ingred Name:O-XYLENE
CAS:95-47-6
Fraction by Wt: 100.0%
===================== Hazards Identification =====================
Reports of Carcinogenicity:NTP:No IARC:No OSHA:No
Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE:
irritation, low body temperature, ringing in the ears, nausea,
vomiting, stomach pain, headache, drowsiness, symptoms of
drunkenness, visual disturbances, lung congestion, kidney damage,
liver damage, coma LONG TERM EXPOSURE: same as effects reported in
short term exposure, tingling sensation, menstrual disorders,
infertility, blood disorders, reproductive effects SKIN CONTACT:
SHORT TERM EXPOSURE: irritation, blisters LONG TERM EXPOSURE: same
as effects reported in short term exposure, rash EYE CONTACT: SHORT
TERM EXPOSURE: irritation (possibly severe), tearing LONG TERM
EXPOSURE: same as effects reported in short term exposure, blurred
vision INGESTION: SHORT TERM EXPOSURE: same as effects reported in
short term inhalation, digestive disorders, aspiration hazard LONG
TERM EXPOSURE: reproductive effects
Medical Cond Aggravated by Exposure:
======================= First Aid Measures =======================
First Aid: INHALATION: If adverse effects occur, remove to
uncontaminated area. Give artificial respiration if not breathing.
If breathing is difficult, oxygen should be administered by
qualified personnel. Get immediate medical attention. SKIN CONTACT:
Wash skin with soap and water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical attention, if
needed. Thoroughly clean and dry contaminated clothing and shoes
before reuse. EYE CONTACT: Flush eyes with plenty of water for at
least 15 minutes. Then get immediate medical attention. INGESTION:
If a large amount is swallowed, get medical attention.
===================== Fire Fighting Measures =====================
Flash Point:63 F (17 C)
Autoignition Temp:865 F (463 C)
Lower Limits:0.9%
Upper Limits:6.7%
Extinguishing Media:regular dry chemical, carbon dioxide, water,
regular foam Large fires: Use regular foam or flood with fine water
spray.
Fire Fighting Procedures:Move container from fire area if it can be
done without risk. Cool containers with water spray until well
after the fire is out. Stay away from the ends of tanks. For fires
in cargo or storage area: Cool containers with water from unmanned
hose holder or monitor nozzles until well after fire is out. If
this is impossible then take the following precautions: Keep
unnecessary people away, isolate hazard area and deny entry. Let
the fire burn. Withdraw immediately in case of rising sound from
venting safety device or any discoloration of tanks due to fire.
For tank, rail car or tank truck: Evacuation radius: 800 meters
(1/2 mile). Water may be ineffective.
Unusual Fire/Explosion Hazard:Severe fire hazard. Vapor/air mixtures
are explosive. The vapor is heavier than air. Vapors or gases may
ignite at distant ignition sources and flash back. Electrostatic
discharges may be generated by flow or agitation resulting in
ignition or explosion.
================== Accidental Release Measures ==================
Neutralizing Agent:
====================== Handling and Storage ======================
Handling and Storage Precautions:Store and handle in accordance with
all current regulations and standards. Store and handle in
accordance with all current regulations and standards. Grounding
and bonding required. Protect from physical damage. Store outside
or in a detached building. Store with flammable liquids. Keep
separated from incompatible substances. Keep separated from
incompatible substances. Subject to storage regulations: U.S. OSHA
29 CFR 1910.106. Grounding and bonding required. Keep separated
from incompatible substances.
Other Precautions:
============= Exposure Controls/Personal Protection =============
Respiratory Protection:The following respirators and maximum use
concentrations are drawn from NIOSH and/or OSHA. 900 ppm Any
chemical cartridge respirator with organic vapor cartridge(s). Any
powered, air-purifying respirator with organic vapor cartridge(s).
Any supplied-air respirator. Any self-contained breathing apparatus
with a full facepiece. Escape - Any air-purifying respirator with a
full facepiece and an organic vapor canister. Any appropriate
escape-type, self-contained breathing apparatus. For Unknown
Concentrations or Immediately Dangerous to Life or Health - Any
supplied-air respirator with full facepiece and operated in a
pressure-demand or other positive-pressure mode in combination with
a separate escape supply. Any self-contained breathing apparatus
with a full facepiece.
Ventilation:Provide local exhaust ventilation system. Ventilation
equipment should be explosion-resistant if explosive concentrations
of material are present. Ensure compliance with applicable exposure
limits. Ventilation equipment should be explosion-resistant if
explosive concentrations of material are present. Provide local
exhaust ventilation system.
Protective Gloves:Wear appropriate chemical resistant gloves. Wear
appropriate chemical resistant gloves.
Eye Protection:Wear splash resistant safety goggles. Provide an
emergency eye wash fountain and quick drench shower in the
immediate work area. Wear splash resistant safety goggles with a
faceshield. Provide an emergency eye wash fountain and quick drench
shower in the immediate work area.
Other Protective Equipment:Wear appropriate chemical resistant
clothing.
Supplemental Safety and Health
O-XYLENE: XYLENE: 100 ppm (435 mg/m3) OSHA TWA 150 ppm (651 mg/m3)
OSHA STEL (vacated by 58 FR 35338, June 30, 1993) 100 ppm ACGIH TWA
150 ppm ACGIH STEL 100 ppm (435 mg/m3) NIOSH recommended TWA 10
hour(s) 150 ppm (655 mg/m3) NIOSH recommended STEL
================== Physical/Chemical Properties ==================
Boiling Pt:291 F (144 C)
Melt/Freeze Pt:-13 F (-25 C)
Vapor Pres:5.2 mmHg @ 25 C
Vapor Density:3.7
Spec Gravity:0.8802
pH:Not available
Evaporation Rate & Reference:0.7 (butyl acetate=1)
Solubility in Water:0.0175% @ 20 C
Appearance and Odor:PHYSICAL STATE:liquid APPEARANCE:clear
COLOR:colorless ODOR:sweet odor
Corrosion Rate:
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:Stable at normal temperatures
and pressure.
Stability Condition to Avoid:Avoid heat, flames, sparks and other
sources of ignition. Containers may rupture or explode if exposed
to heat. Keep out of water supplies and sewers.
Hazardous Decomposition Products:Thermal decomposition products: oxides
of carbon Thermal decomposition products: oxides of carbon
Conditions to Avoid Polymerization:Will not polymerize.
=================== Toxicological Information ===================
Toxicological Information:O-XYLENE: TOXICITY DATA: 3617 mg/kg oral-rat
LD50 (Phillips) LOCAL EFFECTS: Irritant: inhalation, skin, eye
ACUTE TOXICITY LEVEL: Moderately Toxic: ingestion TARGET ORGANS:
central nervous system REPRODUCTIVE EFFECTS DATA: Available.
ADDITIONAL DATA: Alcohol may enhance the toxic effects. Stimulants
such as epinephrine may induce ventricular fibrillation.
===================== Ecological Information =====================
Ecological:ECOTOXICITY DATA: FISH TOXICITY: 16400 ug/L 96 hour(s) LC50
(Mortality) Fathead minnow (Pimephales promelas) INVERTEBRATE
TOXICITY: 200 mg/L 24 hour(s) EC100 (Abundance) Water flea (Daphnia
magna) ALGAL TOXICITY: 4200 ug/L 8 hour(s) EC50 (Growth) Green
algae (Selenastrum capricornutum) OTHER TOXICITY: 73000 ug/L 48
hour(s) LC50 (Mortality) Clawed toad (Xenopus laevis)
==================== Disposal Considerations ====================
Waste Disposal Methods:Subject to disposal regulations: U.S. EPA 40 CFR
262. Hazardous Waste Number(s): U239.
=================== MSDS Transport Information ===================
Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME:
Xylenes ID NUMBER: UN1307 HAZARD CLASS OR DIVISION: 3 PACKING
GROUP: II LABELING REQUIREMENTS: Flammable liquid
===================== Regulatory Information =====================
SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY
HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE
III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not
regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS
CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: Yes
REACTIVE: No SUDDEN RELEASE: No SARA TITLE III SECTION 313 (40
CFR 372.65): o-Xylene
Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS
SUBSTANCES (40 CFR 302.4): o-Xylene: 1000LBSRQ OSHA PROCESS SAFETY
(29CFR1910.119): Not regulated.
State Regulatory Information: California Proposition 65: Not regulated.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.